As we already said there is no rule allowing us to deduce the correct preposition. It is even possible that verbs with a similar if not identical meaning use different prepositions to connect an infinitive.
As a rule of thumb it is possible to say that the reflexive form is connected with the preposition
.
| decidersi = to decide oneself |
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Mi sono deciso a andare via. |
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I decided myself to go away. |
| but (non reflexive) decidere = to decide |
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Ho deciso di andare via. |
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I decided to go away. |
| abituarsi = to accustom oneself |
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Si è abituato a alzarsi alle sei della mattina. |
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He accustomed himself to get up at six o' clock in the morning. |
| adattarsi = to accustom |
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Non ci siamo mai potuti adattare a doverci alzare alle sei della mattina. |
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We never accustomed to be obliged to get up at six o'clock in the morning. |
| affanarsi = to strive |
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Mi sono affannato a cercare altre informazioni sulla questione della sicurezza dell' amalgama. |
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I strive to get more information concerning the security of amalgam. |
| affrettarsi = to hurry |
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Mi sono affrettato a rispondergli. |
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I hurried to answer him. |
| aiutare = to help |
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L' ho aiutato a trovare un posto di lavoro. |
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I helped him to find a job. |
| apprendere = to learn |
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Non ha ancora appreso a scrivere il suo nome. |
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He didn't learn already to write his name. |
| arrischiarsi = to dare |
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Se si arrischia a farlo, non è cosciente dei rischi. |
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If he dares to do it, he doesn't know the risks. |
| aspettare = to wait, to hope |
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Aspetto a finirlo domani. |
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I hope to finish it tomorrow. |
| attacare = to start |
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Quando attacco a leggere non riesco a smettere. |
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If I start reading, I can't stop doing it. |